| A practical synthesis of novel hydroxyl-substituted macrocyclic tri-,tetra- and hexa-amines |
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| 作者姓名： | 薛国平 刘勇 吴成泰 |
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| 作者单位： | Department of Chemistry，Wuhan University，Wuhan，Hubei 430072，China，Department of Chemistry，Wuhan University，Wuhan，Hubei 430072，China，Department of Chemistry，Wuhan University，Wuhan，Hubei 430072，China |
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| 基金项目： | Project (No. 29502010) supported by the National Natural Science Foundation of China |
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| 摘 要： | Macrocyclic tri- and tetra-amines containing a hydroxyl group in the ring have been prepared in moderate yields by a 1:1 cyclocondensation of l,3-dichloro-2-propanol with the disodium salt of N-tosylated diethylenetriamine and triethylenetetraamine.In the case of condensation of 1,3-dichloro-2-propanol with the disodium salt of N-tosylated diethylenetriamine,the 2:2 cyclocondensation product,dihydroxyl macrocyclic hexaamine,was also isolated.
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A practical synthesis of novel hydroxyl-substituted macrocyclic tri-,tetra- and hexa-amines |
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| XUE,Guo-Ping LIU,Yong WU,Cheng-Tai.A practical synthesis of novel hydroxyl-substituted macrocyclic tri-,tetra- and hexa-amines[J].Chinese Journal of Chemistry,1998(6). |
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| Authors: | XUE Guo-Ping LIU Yong WU Cheng-Tai |
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| Institution: | XUE,Guo-Ping LIU,Yong WU,Cheng-TaiDepartment of Chemistry,Wuhan University,Wuhan,Hubei 430072,China |
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| Abstract: | Macrocyclic tri- and tetra-amines containing a hydroxyl group in the ring have been prepared in moderate yields by a 1:1 cyclocondensation of l,3-dichloro-2-propanol with the disodium salt of N-tosylated diethylenetriamine and triethylenetetraamine.In the case of condensation of 1,3-dichloro-2-propanol with the disodium salt of N-tosylated diethylenetriamine,the 2:2 cyclocondensation product,dihydroxyl macrocyclic hexaamine,was also isolated. |
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| Keywords: | Macrocyclic polyamine cyclocondensation mesocylic diamine |
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