| Synthesis, Spectroscopic Properties and Crystal Structures of Dibenzyltin（IV） Dithiobenzoate and Chlorodibenzyltin（IV） Thiobenzoate |
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| 引用本文： | 尹汉东,王传华,马春林,房海霞.Synthesis, Spectroscopic Properties and Crystal Structures of Dibenzyltin（IV） Dithiobenzoate and Chlorodibenzyltin（IV） Thiobenzoate[J].中国化学,2004,22(4):404-410. |
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| 作者姓名： | 尹汉东 王传华 马春林 房海霞 |
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| 作者单位： | DepartmentofChemistry,LiaochengUniversity,Liaocheng,Shandong252059,China |
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| 基金项目： | theNationalNaturalScienceFoundationofChina(No.20271025)andtheNaturalScienceFoundationofShandongProvince(No.Z2003B01). |
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| 摘 要： | Two dibenzyltin(IV) complexes with thiobenzoate ligand, (PhCH2)2Sn(SOCPh)2 (1) and (PhCH2)2Sn(C1)SOCPh (2), have been synthesized by the reaction of dibenzyltin(IV) dichloride with thiobenzoic acid in the presence of organic base Et3N and characterized by IR, ^1H NMR spectroscopy and elemental analysis. Their crystal structures were determined by X-ray single crystal diffraction analysis. In the crystals of 1, the tin atom is six-coordinated in a distorted octahedron configuration. In the crystals of 2, the molecular packing in unit cell reveals that the two adjacent molecules are symmetrically linked to each other to form a dimer with intermolecular Sn…C1 distances of 0.3591 (2) nm and the tin atom is five-coordinated in a distorted trigonal bipyramid configuration.
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| 关 键 词： | 联苄基锡（IV）络合物 硫代苯甲酸 合成 晶体结构 分光特性 |
Synthesis, Spectroscopic Properties and Crystal Structures of Dibenzyltin(IV) Dithiobenzoate and Chlorodibenzyltin(IV) Thiobenzoate |
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| YIN,Han-Dong WANG,Chuan-Hua MA,Chun-Lin FANG,Hai-Xa.Synthesis, Spectroscopic Properties and Crystal Structures of Dibenzyltin(IV) Dithiobenzoate and Chlorodibenzyltin(IV) Thiobenzoate[J].Chinese Journal of Chemistry,2004,22(4):404-410. |
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| Authors: | YIN Han-Dong WANG Chuan-Hua MA Chun-Lin FANG Hai-Xa |
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| Institution: | YIN,Han-Dong* WANG,Chuan-Hua MA,Chun-Lin FANG,Hai-Xa Department of Chemistry,Liaocheng University,Liaocheng,Shandong 252059,China |
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| Abstract: | Two dibenzyltin(IV) complexes with thiobenzoate ligand, (PhCH2)2Sn(SOCPh)2 (1) and (PhCH2)Sn(Cl)SOCPh (2), have been synthesized by the reaction of dibenzyltin(IV) dichloride with thiobenzoic acid in the presence of organic base Et3N and characterized by IR, 1H NMR spectroscopy and elemental analysis. Their crystal structures were determined by X‐ray single crystal diffraction analysis. In the crystals of 1, the tin atom is six‐coordinated in a distorted octahedron configuration. In the crystals of 2, the molecular packing in unit cell reveals that the two adjacent molecules are symmetrically linked to each other to form a dimer with intermolecular Sn…Cl distances of 0.3591(2) nm and the tin atom is five‐coordinated in a distorted trigonal bipyramid configuration. |
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| Keywords: | dibenzyltin(IV) complex thiobenzoate synthesis crystal structure |
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