Matrix embedded cobalt-carbon nano-cluster magnets: behavior as room temperature single domain magnets |
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Authors: | N Nishi K Kosugi K Hino and T Yokoyama |
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Institution: | (1) Institute for Molecular Science, Nishigo-naka 38, Myodaiji,Okazaki 444-8585, Japan |
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Abstract: | A new type of Co-C nanoparticles is synthesized from
CH2Cl2 solution of
Co4(CO)1
2 by heating up to 210
°C in a closed vessel. Transmission
electron microscope (TEM) and electron energy loss spectroscopy
(EELS) observation show that the particles are embedded in
amorphous carbon and their average size is 12 nm. The radial
structure function obtained from the extended X-ray absorption
fine structure (EXAFS) of the Co K-edge absorption of the Co-C
nanoparticles provides a Co-C average distance of 2.08 Å and the
Co-Co distances of 3.18 Å and 3.9 (±0.2) Å. The particles
exhibit the magnetic hysteresis curve with a coercive force of
200 Oe at 20 K and 260 Oe at 300 K. The temperature dependence
of the magnetic susceptibility measured under zero-field cooling
and 10 Oe field cooling conditions exhibits the behavior
characteristic of a set of single magnetic domain nanomagnets in
an amorphous carbon matrix. |
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Keywords: | 36 40 -c Atomic and molecular clusters 36 40 Cg Electronic and magnetic properties of
clusters 36 40 Mr Spectroscopy and geometrical structure of
clusters 75 50 Tt Fine-particle systems nanocrystalline
materials |
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