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Polymerization of aniline on bacterial cellulose and characterization of bacterial cellulose/polyaniline nanocomposite films
Authors:Byoung-Ho LeeHyun-Joong Kim  Han-Seung Yang
Institution:a Lab. of Adhesion & Bio-Composites, Program in Environmental Materials Science, Seoul National University, Seoul 151-921, Republic of Korea
b Research Team for Biomass-based Bio-Materials, Research Institute for Agriculture and Life Sciences, Seoul National University, Seoul 151-921, Republic of Korea
c Department of Bioproducts and Biosystems Engineering, University of Minnesota, Saint Paul, MN 55108 6130, USA
Abstract:Bacterial cellulose/polyaniline nanocomposite film was prepared by the chemical oxidative polymerization of aniline with bacterial cellulose. Polyaniline conducting polymer nanocomposite films with bacterial cellulose fibers was prepared and characterized. In nanocomposite film, the bacterial cellulose was fully encapsulated with polyaniline by direct polymerization of the respective monomers using the oxidant and dopant. These bacterial cellulose/polyaniline nanocomposite films materials exhibited the inherent properties of both components. The deposition of a polyaniline on the bacterial cellulose surface was characterized by SEM. XPS revealed a higher doping level of the nanocomposite films doped with p-TSA dopant. From the cyclic voltammetry results, the polyaniline polymer was thermodynamically stable because redox peaks of electrochemical transitions in the voltagrams were maintained in bacterial cellulose/polyaniline nanocomposite films.
Keywords:Bacterial cellulose  Polyaniline  Conducting polymer  Nanocomposite film  Electrical conductivity
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