NO2分子里德堡态的光学-光学双共振多光子离化谱

采用光学-光学双共振多光子离化（Optical-optical double-resonant multiphoton ionization，简称OODR-MPI）技术详细研究了NO2分子里德堡态的能级结构。结果显示，用不同强度的激光作抽运光，尽管NO2分子的OODR-MPI谱均由规则的光谱序列组成，但NO2分子的离化通道存在很大区别，当抽运光强度较高时，NO2分子通过(3+1+1)双共振多光子过程离化；而当抽运光强度较低时，NO2分子通过(1+2+1)双共振多光子过程离化，两种离化机制的最终共振能级属于不同的里德堡态。

Optical—optical double-resonant multiphoton ionization spectra of Rydberg states of nitrogen dioxide

The optical—optical double-resonant multiphoton ionization (OODR-MPI) technique has been applied to the study of the Rydberg states of nitrogen dioxide. The results show that, although the OODR-MPI spectra of NO₂ are composed of regular progression bands at different pump laser intensities, their ionization pathways are different. The NO₂ molecule is ionized through the (3+1+1) double-resonant process as the pump laser intensity is in a high value, or else it is through the (1+2+1) process. The final resonant states in the two ionizing processes have been attributed to different Rydberg states.