| 红外光谱法研究仲辛醇氧化反应 |
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| 引用本文： | 张国宝,张青枝.红外光谱法研究仲辛醇氧化反应[J].光谱学与光谱分析,1998,18(2):158-161. |
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| 作者姓名： | 张国宝 张青枝 |
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| 作者单位： | 河南化学研究所 |
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| 摘 要： | 用红外光谱法研究了浓硝酸氧化仲辛醇合成己酸的反应历程。考察了中间产物硝酸酯，亚硝酸酯，酮类化合物，硝基化合物，有机腈等成分随硝酸用量的变化规律，并对其反应机理进行了探讨。
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| 关 键 词： | 红外光谱 氧化反应 仲辛醇 硝酸 己酸 |
STUDIES ON THE OXIDATION REACTION OF OCTANOL 2 WITH NITRIC ACID BY INFRARED SPECTROSCOPY |
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| G Zhang,G Zhao,Y Wang,Q Zhang,S Zhang,F Lu.STUDIES ON THE OXIDATION REACTION OF OCTANOL 2 WITH NITRIC ACID BY INFRARED SPECTROSCOPY[J].Spectroscopy and Spectral Analysis,1998,18(2):158-161. |
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| Authors: | G Zhang G Zhao Y Wang Q Zhang S Zhang F Lu |
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| Institution: | Henan Institute of Chemistry, 450003 Zhengzhou. |
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| Abstract: | In this paper,the reaction process of oxidation of octanol 2 with nitric acid has been studied by IR spectroscopy.It is found that the main components of non sapoifiable matter are different in different oxidation degrees.The relation between oxidation products and the amount of nitric acid are investigated,the reaction mechanism has also been studied.Experimental results show that the oxidation process of octanol 2 is as follows:first,octanol 2 is oxidated to octanone 2,or to nitrate,nitrite and nitrile copmpounds,then these compounds are reoxidated to caproic acid in the meantime some by products,such as valeric,enanthic acids are also found in oxidated products. |
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| Keywords: | IR spectra Oxidation Octanol 2 Nitric acid Nitrate Hexanoic acid |
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