| Cu(BF4)2,Cu(C3H7COO)2与双(二苯膦基)烷烃配体形成配位化合物的红外光谱 |
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| 引用本文： | 曹健,刘清,张国宝,王颖,邹卫华,杨瑞娜,赵根锁.Cu(BF4)2,Cu(C3H7COO)2与双(二苯膦基)烷烃配体形成配位化合物的红外光谱[J].光谱学与光谱分析,2003,23(2). |
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| 作者姓名： | 曹健 刘清 张国宝 王颖 邹卫华 杨瑞娜 赵根锁 |
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| 作者单位： | 1. 河南省化学研究所,河南,郑州,450002
2. 郑州大学 |
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| 基金项目： | 国家自然科学基金(20271017) |
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| 摘 要： | 用红外光谱法对二苯基膦系列配体及其分别与Cu(BF_4)_2和Cu(C_3H_7COO)_2。形成的系列配位化合物进行了研究,讨论了谱带的归属和Cu(Ⅰ)配合物形成前后相关谱带的变化规律,并参照元素分析、X-射线粉末衍射分析和热重分析的结果,讨论了所形成配位化合物的可能的结构模式。
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| 关 键 词： | 红外光谱 配合物 双(二苯膦基)烷烃 氟硼酸铜 丁酸铜 |
Infrared Spectroscopic Investigation on Complexes Formed from Cupric Fluoborate and Cupric Butyrate with Bis(diphenylphosphino) alkane Ligands |
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| CAO Jian,LIU Qing,ZHANG Guobao,WANG Ying,ZOU Wei-hua,YANG Rui-na and ZHAO Gen-suo Henan Institute of Chemistry,Zhengzhou ,China.Infrared Spectroscopic Investigation on Complexes Formed from Cupric Fluoborate and Cupric Butyrate with Bis(diphenylphosphino) alkane Ligands[J].Spectroscopy and Spectral Analysis,2003,23(2). |
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| Authors: | CAO Jian LIU Qing ZHANG Guobao WANG Ying ZOU Wei-hua YANG Rui-na and ZHAO Gen-suo Henan Institute of Chemistry Zhengzhou China |
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| Institution: | CAO Jian,LIU Qing,ZHANG Guobao,WANG Ying,ZOU Wei-hua,YANG Rui-na and ZHAO Gen-suo Henan Institute of Chemistry,Zhengzhou 450002,China |
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| Abstract: | The Bis (diphenylphosphino) alkane series ligands and its series of complexes formed from Cu(BF4 )2 and respectively were studied by infrared spectral analysis. This paper discusses the spectral classification and the change regularity of related spectra before and after the Cu( I )complexes were formed. The possible structure model of the formed complexes was discussed, based on the element analysis, powder X-ray diffracfion analysis, and thermal gravity analysis. |
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| Keywords: | Infrared spectrum Complex Bis (diphenylphosphino) alkane Cupric fluoborate Cupric butyrate |
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