Properties of ground state and anomalous quantum fluctuations in one-dimensional polaron-soliton systems—the effects of electron-two-phonon interaction and non-adiabatic quantum correlations

Based on the Holstein model Hamiltonian of one-dimensional molecular crystals, by making use of the expansion approach of the correlated squeezed-coherent states of phonon instead of the two-phonon coherent state expansion scheme, the properties of the ground state and the anomalous quantum fluctuations are investigated in a strongly coupled electron-phonon system with special consideration of the electron-two-phonon interaction. The effective renormalization (αi) of the displacement of the squeezed phonons with the effect of the squeezed-coherent states of phonon and both the electron-displaced phonon and the polaron-squeezed phonon correlations have been combined to obtain the anomalous quantum fluctuations for the corrections of the coherent state. Due to these non-adiabatic correlations, the effective displacement parameter αi is larger than the ordinary parameter α (0) i . In comparison with the electron-one-phonon interaction (g) corrected as αig, we have found the electron-two-phonon interaction (g1) corrected as αi2 g1 is enhanced significantly. For this reason, the ground state energy (E(2) 0 ) contributed by the electron-two-phonon interaction is more negative than the single-phonon case (E(1) 0 ) and the soliton solution is more stable. At the same time, the effects of the electron-two-phonon interaction greatly increase the polaron energy and the quantum fluctuations. Furthermore, in a deeper level, we have considered the effect of the polaron-squeezed phonon correlation (f-correlation). Since this correlation parameter f > 1, this effect will strengthen the electron-one and two-phonon interactions by fαig and f2αi2 g1, respectively. The final results show that the ground state energy and the polaron energy will appear more negative further and the quantum fluctuations will gain further improvement.

Properties of ground state and anomalous quantum fluctuations in one-dimensional polaron-soliton systems--the effects of electron-two-phonon interaction and non-adiabatic quantum correlations

Based on the Holstein model Hamiltonian of one-dimensional molecular crystals, by making use of the expansion approach of the correlated squeezed-coherent states of phonon instead of the two-phonon coherent state expansion scheme, the properties of the ground state and the anomalous quantum fluctuations are investigated in a strongly coupled electron-phonon system with special consideration of the electron-two-phonon interaction. The effective renormalization (ã_i) of the displacement of the squeezed phonons with the effect of the squeezed-coherent states of phonon and both the electron-displaced phonon and the polaron-squeezed phonon correlations have been combined to obtain the anomalous quantum fluctuations for the corrections of the coherent state. Due to these non-adiabatic correlations, the effective displacement parameter ã_i is larger than the ordinary parameter α_i⁽⁰⁾. In comparison with the electron-one-phonon interaction (g) corrected as ã_i, we have found the electron-two-phonon interaction (g₁) corrected as ã_i²g₁ is enhanced significantly. For this reason, the ground state energy (E₀⁽²⁾) contributed by the electron-two-phonon interaction is more negative than the single-phonon case (E₀⁽¹⁾) and the soliton solution is more stable. At the same time, the effects of the electron-two-phonon interaction greatly increase the polaron energy and the quantum fluctuations. Furthermore, in a deeper level, we have considered the effect of the polaron-squeezed phonon correlation (f-correlation). Since this correlation parameter f>1, this effect will strengthen the electron-one and two-phonon interactions by fã_ig and f²ã_i²g₁, respectively. The final results show that the ground state energy and the polaron energy will appear more negative further and the quantum fluctuations will gain further improvement.