| 二维层状配位聚合物[Na（C_6H_6NSO_3）（H_2O）_2]_n的合成及晶体结构表征 |
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| 引用本文： | 黄妙龄,马鹏.二维层状配位聚合物[Na（C_6H_6NSO_3）（H_2O）_2]_n的合成及晶体结构表征[J].光谱实验室,2011,28(5):2272-2275. |
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| 作者姓名： | 黄妙龄 马鹏 |
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| 作者单位： | 泉州师范学院化学与生命科学学院 福建省泉州市东海大街362000 |
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| 基金项目： | 泉州师范学院硕士学位授予单位立项建设化学学科资助项目 |
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| 摘 要： | 采用常规溶液法合成了配位聚合物Na（C6H6NSO3）（H2O）2]n。该聚合物为正交晶系,Pbca空间群,晶胞参数为：a=1.0091（5）nm,b=0.7948（4）nm,c=2.4004（12）nm,V=1.9253（16）nm3,Z=4。中心钠离子有6个氧原子与之配位,形成畸变的八面体配位环境。每个钠离子的配位环境均一样,相邻钠离子通过配位水分子和配体磺酸基上的氧原子相连,将配合物扩展为二维层状结构。
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| 关 键 词： | 对氨基苯磺酸 钠配合物 晶体结构 |
Synthesis and Characterization of Crystal Structure of Two-Dimensional Layer Coordination Polymer:[Na(C_6H_6NSO_3)(H_2O)_2]_n |
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| HUANG Miao-Ling,MA Peng.Synthesis and Characterization of Crystal Structure of Two-Dimensional Layer Coordination Polymer:[Na(C_6H_6NSO_3)(H_2O)_2]_n[J].Chinese Journal of Spectroscopy Laboratory,2011,28(5):2272-2275. |
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| Authors: | HUANG Miao-Ling MA Peng |
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| Institution: | HUANG Miao-Ling MA Peng(College of Chemistry and Life Science,Quanzhou Normal University,Quanzhou,Fujian 362000,P.R.China) |
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| Abstract: | The title compound,Na(C6H6NSO3)(H2O)2]n,was synthesized by routine solution method,and its crystal structure was determined by X-ray diffraction analysis.The crystal is of orthorhombic,space group Pbca with a=1.0091(5)nm,b=0.7948(4)nm,c=2.4004(12)nm,V=1.9253(16)nm3,Z=4.Center Na ion has a distorted octahedral geometry with coordination of 6 O atoms,and each Na has the same coordination condition.The adjacent Na combined with O atoms through water ligand and sulfo group ligand.The complex shows a two-dimens... |
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| Keywords: | p-Aminobenzenesulfonilic Acid Sodium Coordination Crystal Structure |
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