| 具有五配位Zn中心的微孔金属有机 |
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| 引用本文： | 何高飞,柯燕雄,陆舍铭,黄飞,李健民.具有五配位Zn中心的微孔金属有机[J].化学物理学报,2002,15(4):307-311. |
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| 作者姓名： | 何高飞 柯燕雄 陆舍铭 黄飞 李健民 |
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| 作者单位： | 中国科学技术大学化学物理系 合肥230026
(何高飞，柯燕雄，陆舍铭，黄飞)，中国科学技术大学化学物理系 合肥230026(李健民) |
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| 基金项目： | 国家自然科学基金资助项目 (2 0 0 710 30、5 0 0 72 0 2 6 )~~ |
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| 摘 要： | 在有机溶剂THF中 ,合成了一个新颖的、以对苯二甲酸 (BDC)和三乙烯二胺为桥联配体、具有二维骨架结构的金属有机微孔配合物Zn2 (BDC) (DABCO) (H2 O) 2 ,并对其进行了单晶结构解析 ,证实该晶体结构属单斜晶系 ,空间群C2 /c ,a =10 .871(17) ,b =19.10 (3) ,c=7.15 5 (11) ,α=90 ,β =115 .99(3) ,γ =90 ,Z =8,V =1335 (4 ) ,Dc=2 .0 85 g/cm3 ,R =0 .0 85 8.
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| 关 键 词： | 溶剂热合成 配合物 晶体结构 二维骨架 |
| 收稿时间： | 2001/6/23 0:00:00 |
Solvothermal Synthesis and Characterization of An Organic Ligands Bridging Zinc Complex with Porous Structure |
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| He Gaofei,Ke Yanxiong,Lu Seming,Huang Fei and Li Jianmin.Solvothermal Synthesis and Characterization of An Organic Ligands Bridging Zinc Complex with Porous Structure[J].Chinese Journal of Chemical Physics,2002,15(4):307-311. |
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| Authors: | He Gaofei Ke Yanxiong Lu Seming Huang Fei and Li Jianmin |
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| Institution: | Department of Chemical Physic, University of Science and Technology of China, 230026,Department of Chemical Physic, University of Science and Technology of China, 230026,Department of Chemical Physic, University of Science and Technology of China, 230026,Department of Chemical Physic, University of Science and Technology of China, 230026,Department of Chemical Physic, University of Science and Technology of China, 230026 |
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| Abstract: | |
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| Keywords: | Solvothermal synthesis Complex Crystal structure Two-dimensional network |
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