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Y3Al5O12:Ce3+,Cr3+和Y3Al5O12:Ce3+,pr3+,Cr3+荧光粉体系中的能量传递
引用本文:王磊,张霞,郝振东,骆永石,王笑军,张家骅.Y3Al5O12:Ce3+,Cr3+和Y3Al5O12:Ce3+,pr3+,Cr3+荧光粉体系中的能量传递[J].发光学报,2011,32(5):417-422.
作者姓名:王磊  张霞  郝振东  骆永石  王笑军  张家骅
作者单位:1. 中国科学院 激发态重点实验室 长春光学精密机械与物理研究所, 吉林 长春 130033; 2. 中国科学院 研究生院, 北京 100039; 3. 美国乔治亚南大学 物理系, 美国 乔治亚 30460
基金项目:国家自然科学基金,国家科技部项目,吉林省科技发展计划项目,中国科学院创新项目资助
摘    要:通过在YAG:Ce3+和YAG:Ce3+,pr3+荧光粉体系中分别掺入Cr3+离子来提高蓝光管芯白光LED的显色指数.Cr3+离子的加入,增加了红光发射,这归因于Cr3+的2E-4 A2跃迁的零声子线和声子边带发光.Ce3+→Cr3+的能量传递是增强红光发射的重要方式,在YAG:Ce3+,Cr3+体系中,由发射光谱得到...

关 键 词:YAG  能量传递  WLED
收稿时间:2010-11-16

Energy Transfer in Y_3Al_5O_(12):Ce~(3+),Cr~(3+) and Y_3Al_5O_(12):Ce~(3+),Pr~(3+),Cr~(3+) Phosphors
WANG Lei,ZHANG Xia,HAO Zhen-dong,LUO Yong-shi,WANG Xiao-jun,ZHANG Jia-hua.Energy Transfer in Y_3Al_5O_(12):Ce~(3+),Cr~(3+) and Y_3Al_5O_(12):Ce~(3+),Pr~(3+),Cr~(3+) Phosphors[J].Chinese Journal of Luminescence,2011,32(5):417-422.
Authors:WANG Lei  ZHANG Xia  HAO Zhen-dong  LUO Yong-shi  WANG Xiao-jun  ZHANG Jia-hua
Institution:1. Key Laboratory of Excited State Processes, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, 3888 Eastern South Lake Road, Changchun 130033, China; 2. Graduate School of Chinese Academy of Sciences, Beijing 100039, China; 3. Department of Physics, Georgia Southern University, Statesboro, Georgia 30460, USA
Abstract:Triply doped Y_3Al_5O_(12):Ce~(3+),Pr~(3+),Cr~(3+)phosphors with Ce~(3+)and Pr~(3+)substituting for Y~(3+)sites and Cr~(3+)substituting for Al~(3+)site are prepared by solid state reaction.A broad emission spectrum composed a yellow emission band from Ce~(3+),a light red emission line from Pr~(3+)and a deep red emission line from Cr~(3+), which are generated through energy transfer among the dopant ions.The study of photoluminescence and fluorescence decay indicates that there exist energy transfers from Ce...
Keywords:YAG  WLED
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