A useful synthetic equivalent of an acetone enolate |
| |
| Authors: | Veselin Maslak Zorana Ferjancic |
| |
| Institution: | a Faculty of Chemistry, University of Belgrade, Studentski trg 16, PO Box 51, 11158 Belgrade, Serbia
b Faculty of Pharmacy, University of Belgrade, Vojvode Stepe 450, 11000 Belgrade, Serbia |
| |
| Abstract: | 2-Methoxymethoxy-3-chloropropene derived organometallics act as synthetic equivalents of an acetone enolate. Indium-promoted reaction of this reagent with aldehydes affords aldol adducts in moderate to excellent yields. When the reaction was performed with zinc, aldol products were isolated in protected form as the corresponding MOM-enol ethers. |
| |
| Keywords: | Allylation Aldehydes Indium Zinc Aldol reaction Water |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
