Mesoporous aluminosilicate nanocage-catalyzed three-component coupling reaction: an expedient synthesis of α-aminophosphonates |
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| Authors: | Ajayan Vinu Pranjal Kalita Hamid Oveisi Ajayan Mano BV Subba Reddy |
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| Institution: | a International Center for Materials Nanoarchitectonics, WPI Research Center, National Institute for Materials Science, 1-1 Namiki, Tsukuba 305-0044, Japan
b Discovery Laboratory, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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| Abstract: | Here we demonstrate for the first time the synthesis of α-aminophosphonates through the three-component coupling reaction of aldehydes, amines, and diethyl phosphite by using highly acidic 3D mesoporous aluminosilicate nanocage catalyst, which gave excellent yield with a high selectivity in a short reaction time due to its high acidity, 3D pores, and a huge space in the nanocages. |
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| Keywords: | Catalysis Synthesis Mesoporous Heterogeneous Aminophosphonates |
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