| 固相反应法制备磷钼酸(H3PMo12O40)掺杂聚苯胺对其电化学活性的影响 |
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| 引用本文： | 如仙古丽·加玛力,张校刚,吐尔逊·阿不都热依木.固相反应法制备磷钼酸(H3PMo12O40)掺杂聚苯胺对其电化学活性的影响[J].分析测试学报,2007,26(1):70-72,76. |
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| 作者姓名： | 如仙古丽·加玛力 张校刚 吐尔逊·阿不都热依木 |
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| 作者单位： | 新疆大学,化学化工学院,新疆,乌鲁木齐,830046;新疆大学,化学化工学院,新疆,乌鲁木齐,830046;新疆大学,化学化工学院,新疆,乌鲁木齐,830046 |
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| 基金项目： | 国家自然科学基金资助项目(20403014)，中科院“西部之光”及新疆大学青年启动基金资助项目(100096) |
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| 摘 要： | 利用固相反应法制备了磷钼酸(H3PMo12O40,简称PMA)掺杂聚苯胺,并以红外光谱(FT-IR)、X-射线衍射(XRD)、循环伏安(cyclic voltamm ogram)等测试方法对聚苯胺进行了表征。结果表明,无论是液相法还是固相法,磷钼酸掺杂于聚苯胺中,仍保持自身结构特征,与传统液相合成的磷钼酸掺杂聚苯胺相比,固相反应法合成的磷钼酸掺杂聚苯胺的晶化率和电活性略差。固相反应法制备的磷钼酸掺杂聚苯胺在对抗坏血酸(AH2)电催化氧化中,表现出比液相合成更好的电催化活性。
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| 关 键 词： | 聚苯胺 磷钼酸 固相反应 电催化 |
| 文章编号： | 1004-4957（2007）01-0070-03 |
| 收稿时间： | 2005-11-26 |
| 修稿时间： | 2005-11-262006-01-06 |
Effect of the Solid-state Polymerization of Polyaniline Doped with H3PMo12O40 on Its Electrochemical Activity |
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| JAMAL Ruxangul,ZHANG Xiao-gang,ABDIRYIM Tursun.Effect of the Solid-state Polymerization of Polyaniline Doped with H3PMo12O40 on Its Electrochemical Activity[J].Journal of Instrumental Analysis,2007,26(1):70-72,76. |
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| Authors: | JAMAL Ruxangul ZHANG Xiao-gang ABDIRYIM Tursun |
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| Institution: | School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China |
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| Abstract: | Polyaniline doped with H3PMo12O40 was prepared by solid-state polymerization method and characterized by FT-IR,SEM,XRD and cyclic voltammogram,respectively.The effect of solid-state polymerization of polyaniline doped with H3PMo12O40 on its electrocatalysis activity was also discussed.Results showed that polyaniline doped with H3PMo12O40 prepared by solid-state polymerization method had good order and crystallinity,and displayed good electrochemical stability.On the contrary,polyaniline doped with H3PMo12O40 prepared by solid-state polymerization method had higher electrocatalysis activity than that of polyaniline doped with H3PMo12O40 prepared by liquid phase polymerization method. |
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| Keywords: | Polyaniline H3PMo12O40 Solid-state reaction Electrocatalysis |
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