| 甲基丙烯酸丁酯的Nd（Oct）3—Al（i—Bu）3配合催化聚合 |
| |
| 引用本文： | 孙俊全,王光明.甲基丙烯酸丁酯的Nd（Oct）3—Al（i—Bu）3配合催化聚合[J].应用化学,1993,10(4):1-4. |
| |
| 作者姓名： | 孙俊全 王光明 |
| |
| 作者单位： | 浙江大学高分子科学与工程系，浙江大学高分子科学与工程系，浙江大学高分子科学与工程系 310027 杭州，310027 杭州，310027 杭州 |
| |
| 摘 要： | 甲基丙烯酸丁酯(BMA)在2-乙基己酸钕Nd(Oct)_3]和三异丁基铝Al(i-Bu)_3]配合催化下的聚合反应结果表明。以正己烷和石油醚为溶剂的聚合转化率高于甲苯和四氢呋喃体系。4种不同配体的钕盐的聚合转化率差别不大。但是,以Nd(Oet)_3-Al(i-Bu)_3为催化剂时聚甲基丙烯酸丁酯的分子量最高。聚合反应速度与单体浓度和催化剂浓度均成一次方关系。甲基丙烯酸丁酯的聚合反应活化能为47.40kJ/mol。
|
| 关 键 词： | 甲基丙烯酸酯 配位聚合 钕络合物 |
| 收稿时间： | 1992-12-02 |
COORDINATION POLYMERIZATION OF BUTYL METHACRYLATE WITH Nd(Oct)_3-Al(i-Bu)_3 |
| |
| Sun Junquan,Wang Guangming,and Shen Zhiquan.COORDINATION POLYMERIZATION OF BUTYL METHACRYLATE WITH Nd(Oct)_3-Al(i-Bu)_3[J].Chinese Journal of Applied Chemistry,1993,10(4):1-4. |
| |
| Authors: | Sun Junquan Wang Guangming and Shen Zhiquan |
| |
| Abstract: | In the polymerization of butyl methacrylate catalyzed by Nd(Oct)_3-Al(i-Bu)_3, the conversion in hexane and petroleum ether was found to be higher than that observed in toluene and tetrahydrofuran. The combination of Al(i-Bu)_3 with Nd(Oct)_3 gave the polymer of higher molecular weight than other Nd-complexes:Nd(P_(204))_3, Nd(P_(507))_3 and Nd(naph)_3. Kinetics study showed that the rate of polymerization is first order with respect to the monomer and catalyst concentration. The activation energy of polymerization of butyl methacrylate is 47. 4kJ/mol. |
| |
| Keywords: | butyl methacrylate coordination polymerization neodymium complex Ziegler-Natta catalyst |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《应用化学》浏览原始摘要信息 |
| 点击此处可从《应用化学》下载免费的PDF全文 |
