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Structural and optical properties of Mn-doped ZnO nanocrystalline thin films with the different dopant concentrations
Institution:1. Department of Materials Science & Engineering, Yunnan University, 650091 Kunming, People?s Republic of China;2. Advanced Analysis and Measurement Center, Yunnan University, 650091 Kunming, People?s Republic of China;3. State Key Lab of Silicon Materials, Zhejiang University, Hangzhou 310027, People?s Republic of China;1. University School of Basic and Applied Sciences, GGS Indraprastha University, Delhi 110078, India;2. Department of Physics, Swami Shraddhanand College, University of Delhi, Delhi 110036, India;1. Institute of Micro-engineering and Nanoelectronics, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia;2. Physics and Astronomy Department, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia;3. Materials Science and Technology Division (MST-7), Los Alamos National Laboratory, Los Alamos, NM 87545, USA;4. Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8520, Japan;5. Physica Faculty, Eastern European university, Lutsk, Voli 6, Ukraine;6. Faculty of Electrical Engineering, Czestochowa University technology, Armii Krajowej 17, PL-42201 Czestochowa, Poland;1. Photonics Laboratory, Physics Department, Kharazmi University, Tehran, Iran;2. Physics Department, Hakim Sabzevari University, Sabzevar, Iran;1. State Key Laboratory of Software Development Environment and Department of Physics, Beihang University, Beijing 100191, China;2. Faculty of Engineering, The University of Nottingham Ningbo, Ningbo 315100, China;3. School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191, China;1. Department of Biochemistry, University of Zürich, Winterthurestrasse 190, CH-8057 Zürich, Switzerland;2. DICeA, Università di Firenze, via Santa Marta 3, I-50139 Firenze, Italy;1. Russian Armenian (Slavonic) University, Yerevan 0051, Armenia;2. Department of Medical Physics, Yerevan State Medical University, Yerevan 375025, Armenia
Abstract:The transparent nanocrystalline thin films of undoped zinc oxide and Mn-doped (Zn1?xMnxO) have been deposited on glass substrates via the sol–gel technique using zinc acetate dehydrate and manganese chloride as precursor. The as-deposited films with the different manganese compositions in the range of 2.5–20 at% were pre-heated at 100 °C for 1 h and 200 °C for 2 h, respectively, and then crystallized in air at 560 °C for 2 h. The structural properties and morphologies of the undoped and doped ZnO thin films have been investigated. X-ray diffraction (XRD) spectra, scanning electron microscopy (SEM), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) were used to examine the morphology and microstructure of the thin films. Optical properties of the thin films were determined by photoluminescence (PL) and UV/Vis spectroscopy. The analyzed results indicates that the obtained films are of good crystal quality and have smooth surfaces, which have a pure hexagonal wurtzite ZnO structure without any Mn related phases. Room temperature photoluminescence is observed for the ZnO and Mn-doped ZnO thin films.
Keywords:Nanocrystalline films  Mn-doped ZnO  Sol–gel method  Photoluminescence
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