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X射线荧光光谱研究粮食中生命有机碳与碳化学循环
作者姓名:Duan DL  Bian FY  Yuan B  Wang S  Ge MF  Zhang XK  Xu SC
作者单位:1. 云南大学化学科学与工程学院,自然资源药物化学教育部重点实验室,云南昆明650091
2. 中国科学院化学研究所,分子动态与稳态结构国家重点实验室,北京100080
3. 云南大学化学科学与工程学院,自然资源药物化学教育部重点实验室,云南昆明650091;中国科学院化学研究所,分子动态与稳态结构国家重点实验室,北京100080
摘    要:采用X射线荧光光谱(XRF)方法测定六种粮食:稻谷(大米)、小麦(面粉)、黄豆、小米、高粱和玉米中生命有机碳含量和化学元素组成,建立一种新方法测定它们的蛋白质含量.粮食中生命有机碳平均含量约为44%.黄豆中的蛋白质含量最高(42.74%),小米蛋白质含量28.56%,麦子蛋白质含量27.57%,玉米蛋白质含量24.99...

关 键 词:粮食  元素组成  XRF  CO2  温室效应  碳循环

X-ray fluorescence spectrum studies on bioorganic carbon in cereals and carbon chemical circulation
Duan DL,Bian FY,Yuan B,Wang S,Ge MF,Zhang XK,Xu SC.X-ray fluorescence spectrum studies on bioorganic carbon in cereals and carbon chemical circulation[J].Spectroscopy and Spectral Analysis,2011,31(5):1428-1434.
Authors:Duan De-liang  Bian Fu-yong  Yuan Bo  Wang Shu  Ge Mao-fa  Zhang Xing-kang  Xu Si-chuan
Institution:Key Laboratory of Ministry of Education for Medicinal Chemistry of Natural Resource, College of Chemical Science and Technology, Yunnan University, Kunming 650091, China.
Abstract:The bioorganic carbon contents and chemical element compositions in six kinds of cereals: paddy (rice), wheat (flour), soybean, millet, sorghum and corn were determined by X-ray fluorescence (XRF) spectrum, meanwhile a new method was established to probe their protein contents. In the cereals, the average bioorganic carbon content is about 440%. The highest protein content is 42.74% from soybean, and other protein content is 28.56% in millet, 27.57% in wheat, 24.99% in corn, 22.21% in sorghum, but only 20.31% in rice. Based on our new definition of carbon chemical circulation presented in the current work, the authors have found that in 2009 humankind used bioorganic carbon to discharge CO2 into the earth's atmosphere that accounts for one percent of the total CO2 discharge, and consumed organic carbon to release CO2 into the earth's atmosphere, accounting for 10.73% of the total CO2 discharge. The clear definition of carbon chemical circulation and the discharged CO2 content from the distinct types of carbon compounds would advance the study on carbon chemical circulation and the atmospheric CO2 greenhouse effect. Our work further found that it takes eight years to circulate the total earth's atmospheric CO2. The short period shows the sensitivity for CO2 to keep its dynamical equilibrium in the earth's atmosphere. However, no experimental data has been reported to prove a heavy destructive greenhouse effect of CO2 existing in the earth's atmosphere.
Keywords:XRF  CO2
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