| 气相色谱法研究配位化合物的热稳定性 II.草酸配位化合物的热分解动力学 |
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| 引用本文： | 汪信,吴沛成,忻新泉,戴安邦.气相色谱法研究配位化合物的热稳定性 II.草酸配位化合物的热分解动力学[J].化学学报,1983,41(1):48-55. |
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| 作者姓名： | 汪信 吴沛成 忻新泉 戴安邦 |
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| 作者单位： | 南京大学配位化学研究所 |
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| 摘 要： |
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| 关 键 词： | 气相色谱 络合物 热稳定性 动力学方程 草酸根络合物 热分解 |
Studies on thermal stabilities of coordination compounds by gas chromatography. ii. Kinetics of thermal decomposition of oxalato coordination compounds. |
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| WANG XIN,WU PEICHENG,XIN XINQUAN,DAI ANBANG.Studies on thermal stabilities of coordination compounds by gas chromatography. ii. Kinetics of thermal decomposition of oxalato coordination compounds.[J].Acta Chimica Sinica,1983,41(1):48-55. |
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| Authors: | WANG XIN WU PEICHENG XIN XINQUAN DAI ANBANG |
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| Abstract: | In this paper kinetics of thermal decomposition of oxalato coordination is stuided by gas chromatography. A kinetic equation of thermal decomposition is proposed. A computer program which was written in FORTRAN-IV language has been worked out to evaluate the activation energy and the Arrhenius pre-exponential factor. The results of calculation show that the equation is better agreement with the experimantal data. The activation step in decomposition of Fe(C2H4)3 is discussed on basis of calculation by EHMO method. |
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| Keywords: | GAS CHROMATOGRAPHY COMPLEX COMPOUNDS THERMAL STABILITY KINETICS EQUATIONS OXALATO COMPLEX THERMAL DECOMPOSITION |
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