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Photocatalytic oxidation of primary and secondary benzylic alcohols to carbonyl compounds catalyzed by H3PW12O40/SiO2 under an O2 atmosphere |
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| Authors: | Saeid Farhadi Mozhgan Afshari Mansoureh Maleki Zaynab Babazadeh |
| Institution: | Department of Chemistry, University of Lorestan, Khoramabad 68135-465, Iran |
| Abstract: | An efficient, selective and green procedure for the photocatalytic oxidation of primary and secondary benzylic alcohols to the corresponding aldehydes and ketones has been achieved using silica-encapsulated H3PW12O40 as a recyclable heterogeneous photocatalyst in acetonitrile under oxygen gas as the sole reoxidant of the catalyst. |
| Keywords: | Benzylic alcohols Photocatalytic Oxidation Polyoxometalates Silica-encapsulated H3PW12O40 |
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