Application of various ionic liquids as cosolvents for chloroperoxidase-catalysed biotransformations |
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| Authors: | Roman J Lichtenecker Walther Schmid |
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| Institution: | 1.Institute of Organic Chemistry,University of Vienna,Vienna,Austria |
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| Abstract: | Abstract Chloroperoxidase from Caldariomyces fumago catalyses oxidation of indole and thioanisole in reaction mixtures containing up to 40% (v/v) of different ionic liquids (ILs). Results indicate that ILs containing tosylate, trifluoroacetate, chloride, and methylsulfate
anions are suitable cosolvents for these transformations, yielding high enantiomeric excess and good conversion rates.
Graphical abstract  |
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| Keywords: | Caldariomyces fumago Sulfoxides Chirality Oxidation Ionic liquids |
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