A Cyclic Hexanuclear Heterometalladithiolene Cluster [{(Cp*Rh)2Mo(μ‐CO)2(CO)}2(S2C6H2S2)2] with Two π‐Conjugated S2C6S2 Bridges: Synthesis,Crystal Structure,and Properties
1. Department of Chemistry, School of Science, The University of Tokyo, 7‐3‐1 Hongo, Bunkyo‐ku, Tokyo 113‐0033 (Japan), Fax: (+81)?3‐5841‐8063, http://utsc2.chem.s.u‐tokyo.ac.jp/～inorg/indexe.html;2. Permanent address: Chemistry and Chemical Engineering College, Inner Mongolia University, Hohhot 010021 (China)
Abstract:
Two dragons playing ball : Direct metal–metal bond formation using a π‐conjugated dinuclear metalladithiolene complex with two electron‐deficient metal centers as building blocks led to a cyclic double trinuclear heterometalladithiolene cluster with two parallel plane bridges (see structure; Rh pink, Mo green, S yellow, C gray, O red).
