配合物稳定性与酸碱强度之间的直线自由能关系——ⅪⅤ.N-(取代苯基)亚氨基二乙酸与铜(Ⅱ)、镍(Ⅱ)、锌(Ⅱ)钴(Ⅱ)二元配合物的稳定性研究 |
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引用本文: | 刘树祥,林华宽,刘在均,王光,陈荣悌.配合物稳定性与酸碱强度之间的直线自由能关系——ⅪⅤ.N-(取代苯基)亚氨基二乙酸与铜(Ⅱ)、镍(Ⅱ)、锌(Ⅱ)钴(Ⅱ)二元配合物的稳定性研究[J].无机化学学报,1992,8(1):78-81. |
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作者姓名: | 刘树祥 林华宽 刘在均 王光 陈荣悌 |
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作者单位: | 南开大学化学系, 天津300071;东曲阜师范大学化学系,南开大学化学系, 天津300071,南开大学化学系, 天津300071,南开大学化学系, 天津300071,南开大学化学系, 天津300071 |
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摘 要: | The dissociation constants of N-(para-substituted phenyl) iminodiacetic acid (p-RPhID A, R= Cl, H, CH3, CH3O) and N-(ortho-substituted phenyl) iminodiacetic acid (o-RPhlDA) and the formation constants of binary complex compounds of Cu(Ⅱ)-o-RPhIDA, Cu(Ⅱ)-p-RPhIDA, Co(Ⅱ)-p-RPhIDA, Ni(Ⅱ)-p-RPhIDA and Zn(Ⅱ)-p-RPhIDA were determined by pH method in the presence 0.1mol·dm-3KNO3 at 25℃ . It has been found that linear free energy relationships not only exist between stability of these binary complex compounds and base strength of ligand, but also exist between logβ and σ'(=pK2-pK2).The deviation of Cu(Ⅱ)-o-CH3PhIDA from linearity may be ascribed to steric effect of methyl group at ortho position.
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关 键 词: | 铜 镍 锌 钴 配合物 稳定性 |
收稿时间: | 1989/10/13 0:00:00 |
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