ICPI—AES直接测定氯化稀土和轻稀土中稀土元素

以电荷耦合器件为检测器的ＩＣＰ－ＡＥＳ光谱仪直接测定混合稀土中的十五种稀土元素。考察十五种稀土元素的五十余条灵敏线的谱图，分析稀土元素之间的光谱干扰并利用多组分谱图拟合方法扣除空白及元素间的干扰。研究溶液酸度及仪器工作参数的影响，方法回收率为９８．４％￣１０１．７％，相对标准偏差小于２％。

Direct Determination of Rare Earth Elements in Rare Earth Chloride and Light Rare Earth Oxide by ICP-AES

ICP-AES was used for the direct determination of 15 rare earth elements in synthetic solutions and real sample. Spectral interferences between REEs in the mixtures of rare earth were investigated with a high-resolution echelle spectrometer and suitable analytical lines of 15 rare earth elements were selected. The Multicomponent Spectral Fitting(MSF) models were made. The method was used to remove spectral interferences and background. The factors influence the modes were discussed. The influences of acidity and ICP parameters were investigated. The compromise condition of simultaneous determination of 15 REEs was selected. Axially viewed ICP torch was used to determine 15 REEs, The detection limits are Y 0.21 microgram.L-1, La 9.1 micrograms.L-1, Ce 14.1 micrograms.L-1, Pr 1.9 micrograms.L-1, Nd 7.8 micrograms.L-1, Tm 0.37 microgram.L-1, Yb 0.12, Lu microgram.L-1, Ho 0.06 microgram.L-1, Er 0.06 microgram.L-1, Tb 0.53 microgram.L-1, Sm 1.14 micrograms.L-1, Eu 0.09 microgram.L-1, Dy 0.08 microgram.L-1, Gd 0.30 microgram.L-1. The recoveries of this procedure are between 98.4% and 101.7%. The RSD is within 2%. The method is rapid and accuracy.