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Synthesis and Characterization of Heterobimetallic Aluminum‐Germanium(IV) Disulfides |
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| Authors: | Zhi Yang Xiaoli Ma Zhensheng Zhang Herbert W Roesky Prof Dr Drhc Jörg Magull Arne Ringe |
| Institution: | G?ttingen, Institut für Anorganische Chemie der Georg‐August‐Universit?t |
| Abstract: | Three heterobimetallic aluminum‐germanium(IV) disulfides are synthesized. The reaction of {LAl(SLi)2(THF)2]}2 ( 1 ) (L = HC(CMeNAr)2, Ar = 2,6‐iPr2C6H3) with Ph2GeCl2, Me2GeCl2, and GeCl4, respectively, in THF afforded LAl(μ‐S)2GePh2 ( 2 ), LAl(μ‐S)2GeMe2 ( 3 ) and LAl(μ‐S)2Ge(μ‐S)2AlL ( 4 ) in good yields. Compounds 2 , 3 and 4 were investigated by elemental analysis, NMR, EI‐MS and 3 was also characterized by single crystal X‐ray structural analysis. |
| Keywords: | Aluminum Germanium Disulfides Heterobimetallic compounds |