Improvement of thermal stability of sulfonated polyphosphazenes by introducing a self‐crosslinkable group |
| |
Authors: | Hyeoncheol Song Seung Cheol Lee Hye Young Heo Dong Il Kim Dong‐Hwal Lee Ju Ho Lee Ji Young Chang |
| |
Institution: | 1. Department of Materials Science and Engineering, Seoul National University, Seoul 151‐744, Korea;2. Electronics Materials Division, DJIST/R&D 2nd Team, Dongjin Semichem Co. Ltd., Incheon, Korea |
| |
Abstract: | We prepared sulfonated polyphosphazenes having various aryloxy substituents, and studied their thermal stabilities and membrane properties. Sulfonated polyphosphazenes were synthesized by the reaction of polydichlorophosphazene with sodium aryloxides and subsequent sulfonation with fuming sulfuric acid. With increasing the degree of sulfonation, the polymers showed higher proton conductivity, but suffered more from swelling in an aqueous solution. We introduced a hydroxymethylphenoxy group onto the phosphazene backbone as a self‐crosslinkable group by reaction of poly(dichlorophosphazene) and a sodium salt of 4‐hydroxymethylphenol. When a film of a sulfonated polymer having a methylol group was heated at 80 °C under vacuum for 1 h, it became insoluble in NMP, indicating the formation of a network structure. We investigated the crosslinking reaction of the polymers by DSC and FTIR. The crosslinking reaction proceeded only in the sulfonated polymers. Because the sulfonated polymers provide acidic protons, the methylol groups became more electrophilic and reacted with neighboring aromatic rings. A condensation reaction between themselves could also occur. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 5850–5858, 2008 |
| |
Keywords: | crosslinking direct methanol fuel cell membranes polyphosphazenes sulfonated polymers |
|
|