| Octa-membered Water Ring Chain Based on Sulfonic Group in Ni（Ⅱ） Complex with 2-[（E）-（2-Oxidophenyl）methyleneamino] Ethanesulfonato and 2,2＇-Bipyridinyl |
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| 作者姓名： | ZHANG Shu-Hua LI Guang-Zhao ZHONG Fan FENG Xiao-Zhen |
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| 作者单位： | [1]Key Laboratory of Non-ferrous Metal Materials and Processing Technology,（ Guilin University of Technology）, Ministry of Education, Guilin 541004, China [2]State Key Laboratory of CoordinationChemistry, Nanjing University, Nanjing 210093, China [3]Department of Chemistry, Jinggangshan Normal College, Ji＇an 343009, China |
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| 基金项目： | Supported by the Key Laboratocy of Non-ferrous Metal Materials and New Processing Technology, Milfistry of Education and the State Key Laboratory of Coordination Chemislry |
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| 摘 要： | The title compound, Ni（tssb）（2,2-bipy）2].5（H2O） 1 （tssbH2 =2-（E）-（2-oxido- phenyl）methyleneamino]ethanesulfonato, 2,2-bipy = 2,2＇-bipyridinyl）, belongs to orthorhombic, space group Pbcn with a = 20.3983（18）, b = 17.6929（15）, c = 17.0897（15） nm, V= 6167.8（9） nm^3, Mr= 688.38, Z = 8, De = 1.481 g.cm^-3, F（000） = 2880,μ = 0.758 mm-1 and S =1.099. Each NiIr atom is six-coordinated by one N and one O atoms from one tssb^2- anion and four N atoms from two 2,2-bipy ligands to give a distorted octahedral geometry. Noticeably, there exists a rare octa-mem- bered water ring which presents a 1D chain by sulfonic group.
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| 关 键 词： | 镍（Ⅱ） 络合物 甲基 化学分析 |
| 收稿时间： | 2007-01-19 |
| 修稿时间： | 2007-06-11 |
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