| 核壳型PVAc/PBA乳胶粒热力学平衡状态 |
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| 引用本文： | 赵科,孙培勤,刘大壮.核壳型PVAc/PBA乳胶粒热力学平衡状态[J].应用化学,2002,19(7):641-644. |
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| 作者姓名： | 赵科 孙培勤 刘大壮 |
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| 作者单位： | 郑州大学 |
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| 基金项目： | 河南省自然科学基金资助项目 |
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| 摘 要： | 乙酸乙烯酯;形态;核壳型PVAc/PBA乳胶粒热力学平衡状态;核壳结构;丙烯酸丁酯;乳液聚合;
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| 关 键 词： | 乙酸乙烯酯 形态 核壳型PVAc/PBA乳胶粒热力学平衡状态 核壳结构 丙烯酸丁酯 乳液聚合 |
| 文章编号： | 1000-0518(2002)07-0641-04 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2001年11月5日 |
Thermodynamic Equilibrium Morphology of PVAc/PBA Core-Shell Particle |
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| ZHAO Ke,SUN Pei-Qin,LIU Da-Zhuang.Thermodynamic Equilibrium Morphology of PVAc/PBA Core-Shell Particle[J].Chinese Journal of Applied Chemistry,2002,19(7):641-644. |
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| Authors: | ZHAO Ke SUN Pei-Qin LIU Da-Zhuang |
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| Institution: | ZHAO Ke~*,SUN Pei-Qin,LIU Da-Zhuang |
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| Abstract: | The thermodynamically preferred morphology of the composite latex of PVAc/PBA core shell particle in starved condition has been predicted by using the methods of Torza, Sundberg, Gonzalez Ortiz and the simple interfacial tensions calculation. The PVAc/PBA particles having PVAc as shell and PBA as core could be observed in TEM photos. The emulsion of inverted core shell structure has a potential use as an adhesive for degradable food container. |
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| Keywords: | vinyl acetate butyl acrylate emulsion polymerization core shell structure morphology |
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