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Crown ether complexes of tin(II) trifluoromethanesulfonate
Authors:Rajoshree Bandyopadhyay
Institution:Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, Canada N9B 3P4
Abstract:The treatment of tin(II) trifluoromethanesulfonate with three differently-sized crown ethers 12]crown-4, 15]crown-5 and 18]crown-6 results in the formation of tin complexes that exhibit dramatically different structural features. The compounds are investigated using experimental techniques and density functional theory calculations.
Keywords:Main group  Tin  Low valent  Crown ether  Coordination chemistry
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