| 甲基锍盐的合成 |
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| 引用本文： | 王磊.甲基锍盐的合成[J].合成化学,1997(4). |
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| 作者姓名： | 王磊 |
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| 作者单位： | 淮北煤炭师范学院化学系 |
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| 基金项目： | 煤炭系统回国留学人员科技基金 |
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| 摘 要： | 在四氟硼酸银存在下，分别以硫醚、硫醇、硫酚或过硫醚为原料与碘甲烷反应制备了相应的甲基锍盐。用１ＨＮＭＲ和１３ＣＮＭＲ表征产物的结构并提出了反应的机理。
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| 关 键 词： | 甲基锍盐 硫醚 硫醇 硫酚 过硫醚 碘甲烷 |
Synthesis of Methylsulfonium Salt |
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| Wang,Lei.Synthesis of Methylsulfonium Salt[J].Chinese Journal of Synthetic Chemistry,1997(4). |
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| Authors: | Wang Lei |
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| Abstract: | In the presence of silver tetrafluoroborate, sulfides,thiols,thiophenols and disulfides reacted with methyl iodide to form correspounding methylsulfonium salts at room temperature. The chemical shifts of 1H NMR and 13 C NMR of added methyl groups are given and the reaction mechanisms are proposed. |
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| Keywords: | Methylsulfonium salts Sulfides Thiols Thiophenols Disulfides Methyl iodide |
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