| 2-取代芳基苯并[b]呋喃类化合物的合成 |
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| 引用本文： | 庞冀燕,汪波,陈之朋,许遵乐.2-取代芳基苯并[b]呋喃类化合物的合成[J].有机化学,2005,25(2):176-181. |
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| 作者姓名： | 庞冀燕 汪波 陈之朋 许遵乐 |
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| 作者单位： | 中山大学化学与化学工程学院,广州,510275 |
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| 基金项目： | 广东省广州市科技局科研项目 |
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| 摘 要： | 以4-取代苯乙炔化亚铜与3-甲氧基-4-羟基-5-溴肉桂酸甲酯为原料进行缩合反应得到2-取代芳基并b]呋喃, 并将其衍生化, 得到14个2-芳基-5-烷基-7-甲氧基苯并b]呋喃化合物, 并确证了其结构.
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| 关 键 词： | 苯乙炔化亚铜 2-芳基苯并呋喃 合成 |
| 收稿时间： | 2004-3-25 |
| 修稿时间： | 2004年3月25日 |
Synthesis of 2-Arylbenzo[b]furan Derivatives |
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| PANG,Ji-Yan WANG,Bo CHEN,Zhi-Peng XU,Zun-Le.Synthesis of 2-Arylbenzo[b]furan Derivatives[J].Chinese Journal of Organic Chemistry,2005,25(2):176-181. |
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| Authors: | PANG Ji-Yan WANG Bo CHEN Zhi-Peng XU Zun-Le |
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| Institution: | (Department of Applied Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275) |
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| Abstract: | Arylbenzob]furans were obtained via coupling reaction of the copper(I) arylacetylides with the phenylbromide, and then a series of derivatives were designed and synthesized by reduction, Vilsmeier, hydrolysis and substituted reaction. All the compounds were fully characterized by MS, 1H NMR, IR spectra and elemental analysis. |
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| Keywords: | copper(I) arylacetylides 2-benzo[b]furans synthesis |
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