| 钴(II)酞菁与巯基乙醇轴向配位反应的动力学 |
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| 引用本文： | 冯海霞,朱志昂,王传忠,阮文娟,李瑛,陈荣悌.钴(II)酞菁与巯基乙醇轴向配位反应的动力学[J].物理化学学报,1999,15(2):167-172. |
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| 作者姓名： | 冯海霞 朱志昂 王传忠 阮文娟 李瑛 陈荣悌 |
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| 作者单位： | Department of Chemistry,Nankai University,Tianjin 300071 |
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| 基金项目： | 国家自然科学基金!29571019，天津市自然科学基金 |
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| 摘 要： | 用停流法研究了2，9，16，23-四羧基钴（Ⅱ）酞菁与2-巯基乙醇轴向配位的快速反应动力学，提出了较为合理的反应机理，用非线性及线性拟合的方法求得了各基元步骤的动力学参数，探讨了温度、pH等因素对反应的影响．
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| 关 键 词： | 钴(II)酞菁 硫醇 轴配位反应动力学 反应机理 |
| 收稿时间： | 1998-04-24 |
| 修稿时间： | 1998-08-03 |
Kinetics on the Axial Coordination Reaction of Co(II)-2,9,16,23-tetracaboxyphthalocyanine with 2-mercaptoethanol |
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| Feng Haixia, Zhu Zhiang ,Wang Chuanzhong, Ruan Wenjuan, Li Ying ,Chen Yunti.Kinetics on the Axial Coordination Reaction of Co(II)-2,9,16,23-tetracaboxyphthalocyanine with 2-mercaptoethanol[J].Acta Physico-Chimica Sinica,1999,15(2):167-172. |
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| Authors: | Feng Haixia Zhu Zhiang Wang Chuanzhong Ruan Wenjuan Li Ying Chen Yunti |
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| Institution: | Department of Chemistry,Nankai University,Tianjin 300071 |
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| Abstract: | The kinetic studies on the axial coordination reaction of Co(Ⅱ)-2,9,16,23-tetracaboxyphthalocyamine with 2-mercaptoethanol in aqueous solution were studied by stopped flow method. A general mechanism was proposed and the kinetic parameters were obtained by non-liner and liner least-squares program. The effects of temperature and pH on the reaction were investigated in this paper. |
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| Keywords: | Co(II)-Phthalocyanine Thiol Kinetics of axial coordinational reaction Stopped flow method Mechanism |
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