| Ni(II), Pd(II), Pt(II)环戊基(苯基)和膦配合物的低频振动光谱及构型 |
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| 引用本文： | 车迅,宋果男,李同信.Ni(II), Pd(II), Pt(II)环戊基(苯基)和膦配合物的低频振动光谱及构型[J].化学学报,1989,47(10):962-966. |
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| 作者姓名： | 车迅 宋果男 李同信 |
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| 作者单位： | 中国科学院大连化学物理研究所 |
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| 摘 要： | 本工作合成了下述金属配合物: MCl2L2(M=Pd, Pt), NiX2L2(X=Cl, Br, I),L=PPh3-x(C5H9)x(x=0-3), 并研究了它们的远红外光谱和某些低频Raman光谱, 对某些M-P, M-X振动谱带做出了归属, 并提供结构信息。
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| 关 键 词： | 苯基 红外分光光度法 有机磷化合物 铂络合物 三苯基膦 过渡金属络合物 镍络合物 振动谱 钯络合物 构型 |
The low frequency vibrational spectra of some cyclopentyl (phenyl) tertia y phosphine complexes of Ni(II), Pd(II) and Pt(II) |
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| CHE XUN,SONG GUONAN,LI TONGXIN.The low frequency vibrational spectra of some cyclopentyl (phenyl) tertia y phosphine complexes of Ni(II), Pd(II) and Pt(II)[J].Acta Chimica Sinica,1989,47(10):962-966. |
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| Authors: | CHE XUN SONG GUONAN LI TONGXIN |
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| Abstract: | The metal complexes with various cyclopentylphenyl tertiary phosphine ligands, MO2L2, (M = Pd, Pt), NiX2L2, (X = Cl, Br, I), L = PPh3-x(C5H9)(x = 0-3), were synthesized. The far-IR and, where possible, low frequency Raman spectra were studied. The M-P and M-X stretching frequencies of some complexes were assigned by analogy with similar assignments and the geometry information were obtained from their spectroscopic feature. |
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| Keywords: | PHENYL GROUP INFRARED SPECTROPHOTOMETRY ORGANO PHOSPHORUS COMPOUNDS PLATINUM COMPLEX TRIPHENYLPHOSPHINE TRANSITION METAL COMPLEX NICKEL COMPLEX VIBRATIONAL SPECTRA PALLADIUM COMPLEX CONFIGURATION |
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