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Molecular design of ambipolar redox-active molecules II: closed-shell systems |
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| Authors: | Vyacheslav V Sentyurin Oleg A Levitskiy Tatiana V Magdesieva |
| Institution: | Lomonosov Moscow State University, Dept. of Chemistry, Leninskie Gory 1/3, Moscow 119991, Russia |
| Abstract: | This mini-review highlights key structural features that should be taken into account when creating ambipolar redox-active closed-shell metal-free molecules. This type of compound is strongly required for the fabrication of all-organic ‘poleless’ batteries and semiconductors. The suggested strategies aimed at stabilization of both oxidized (cationic) and reduced (anionic) redox-states are based on the comprehensive analysis of the most successful structures taken from the recent publications. |
| Keywords: | Ambipolar organic molecules Structure-redox-properties relationship Molecular design Oxidation Reduction Stabilization of the redox states |
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