Synthesis and oxidation of bis(triphenylgermyl)zinc |
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| Authors: | Masato Nanjo |
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| Institution: | Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan |
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| Abstract: | Bis(triphenylgermyl)zinc (Ph3Ge)2Zn (1), prepared by the reaction of diethylzinc (Et2Zn) with two molar amounts of triphenylgermane (Ph3GeH), was easily reacted by a small amount of oxygen to give tetrameric oxide (Ph3GeZnO)4 (2). Four zinc and four oxygen atoms in 2 are arranged such that a cube is formed as determined by X-ray diffraction analysis. Further oxidation of 2 led to the formation of digermoxane, (Ph3Ge)2O as a final product. |
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| Keywords: | Germylzinc X-ray diffraction Oxidation |
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