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Synthesis of 1,2-allenic ketones through oxidation of homopropargyl alcohols with CrO_3(cat.)/TBHP under MWI |
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| Authors: | Xin Ying Zhang Ying Ying Qu Yang Yang Wang Xue Sen Fan School of Chemistry Environmental Science Henan Key Laboratory for Environmental Pollution Control Henan Normal University Xinxiang China |
| Institution: | School of Chemistry and Environmental Science, Henan Key Laboratory for Environmental Pollution Control, Henan Normal University, Xinxiang 453007, China |
| Abstract: | A CrO_3 catalyzed oxidation of homopropargyl alcohols with tert-butyl hydroperoxide under microwave irradiation was found to be an efficient and rapid alternative for the preparation of 1,2-allenic ketones.The advantages of this procedure include short reaction time,less adverse impact on the environment and reasonably high efficiency. |
| Keywords: | Allenic ketones Oxidation Microwave irradiation Chromium(Ⅵ) oxide tert-Butyl hydroperoxide |
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