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高灵敏度分光光度法测定茶叶中锌的含量
引用本文:陈慧敏,应如梦,王帅,林丝丝,张春牛.高灵敏度分光光度法测定茶叶中锌的含量[J].广东微量元素科学,2011,18(6):37-40.
作者姓名:陈慧敏  应如梦  王帅  林丝丝  张春牛
作者单位:丽水学院化学系,浙江,丽水,323000
基金项目:浙江省新苗人才计划基金
摘    要:研究了在聚乙烯醇(PVA)存在下,Zn2+ - SCN—- RhB高灵敏度显色反应体系,采用分光光度法测定茶叶中微量锌的新方法.结果表明,络合物的最大吸收峰在605 nm处,摩尔吸光系数为1.59×106 L·mol—1·cm—1,Zn2+的质量浓度在0.0~0.04 μg/mL范围内服从比尔定律.该法用于测定茶叶中锌...

关 键 词:分光光度法    罗丹明B  茶叶

Determination of Zinc in Tea Through Highly SensitiveSpectrophotometric System
CHEN Huimin,YING Rumeng,WANG Shuai,LIN Sisi,ZHANG Chunniu.Determination of Zinc in Tea Through Highly SensitiveSpectrophotometric System[J].Trace Elements Science,2011,18(6):37-40.
Authors:CHEN Huimin  YING Rumeng  WANG Shuai  LIN Sisi  ZHANG Chunniu
Institution:CHEN Huimin,YING Rumeng,WANG Shuai,LIN Sisi,ZHANG Chunniu(Department of Chemistry,Lishui College,Zhejiang Lishui 323000,China)
Abstract:A new spectrophotometric method for the determination of zinc in tea by using Zn2+-SCN——RhB-PVA highly sensitive chromogenic reaction system was studied.The results show that the strongest absorption peak of ion complex is at 605 nm and the molar absorption coefficient is 1.59×106L mol-1 cm-1.When the zinc concentration is in the range of 0.0~0.04 μg/mL,which accords with lambert beer’s law.Favorable results can be achieved with this method.
Keywords:spectrophotometry  zinc  rhodamine B  tea  
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