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| Zn~Ⅱ, Ni~Ⅱ, and Mn~Ⅱ Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses,Structures, and Luminescent and Magnetic Properties | |
| 引用本文： | 刘勇路,陈砚美,高倩,刘玮,李亚红,李武.Zn~Ⅱ, Ni~Ⅱ, and Mn~Ⅱ Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses,Structures, and Luminescent and Magnetic Properties[J].结构化学,2014,33(8):1171-1183. |
| 作者姓名： | 刘勇路 陈砚美 高倩 刘玮 李亚红 李武 |
| 作者单位： | [1]Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry,Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China; [2]Key Laboratory of Salt Lake Resources and Chemistry,Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China; [3]State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China |
| 基金项目： | Supported by NNSFC(21272167 and 21201127);the Priority Academic Program Development of Jiangsu Higher Education Institution,Graduate Education Innovation Project in Jiangsu Province(CXZZ12_0808 and CXLX12_0784);KLSLRC(KLSLRC-KF-13-HX-1) |
| 摘 要： | The employment of N-hydroxy-pyridine-2-carboxamidine in the coordination chemistry of zinc(Ⅱ), nickel(Ⅱ) and manganese(Ⅱ) under solvothermal conditions is reported. Four complexes of compositions, Zn2(O2CMe)3{(py)C(NH2)NOH}4](OH)(1), Zn4(OH)2{(py)C(NH2)-NO}4Cl2]·3MeCN(2), Ni(SO4)(H2O){(py)C(NH2)NOH}2]·H2O(3) and Mn(SO4){(py)C(NH2)-NOH}2]n(4), have been synthesized by rationally choosing different metal salts and dexterously employing acetate and sulfate ions as the bridging groups. Luminescent properties for 2 suggested strong emission in the solid state at room temperature. Variable temperature(2.0~300 K) magnetic studies for the linear chain complex 4 indicate weak antiferromagnetic Mn(Ⅱ)···Mn(Ⅱ) exchange interactions. |
| 关 键 词： | 羟基吡啶 发光性能 磁学性质 合成 甲脒 锌 Mn 结构 |
ZnⅡ NiⅡ, and MnⅡ Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine： Syntheses,Structures, and Luminescent and Magnetic Properties |
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| LIU Yong-Lu , CHEN Yan-Mei , GAO Qian , LIU Wei , LI Ya-Hong , LI Wu.ZnⅡ NiⅡ, and MnⅡ Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine： Syntheses,Structures, and Luminescent and Magnetic Properties[J].Chinese Journal of Structural Chemistry,2014,33(8):1171-1183. | |
| Authors: | LIU Yong-Lu CHEN Yan-Mei GAO Qian LIU Wei LI Ya-Hong LI Wu |
| Institution: | 1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry,Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China 2. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry,Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China;Key Laboratory of Salt Lake Resources and Chemistry,Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China 3. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry,Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China;State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China 4. Key Laboratory of Salt Lake Resources and Chemistry,Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China |
| Abstract: | solvothermal, N-hydroxy-pyridine-2-carboxamidine,luminescence, magnetic property |
| Keywords: | solvothermal N-hydroxy-pyridine--carboxamidine luminescence magnetic property |
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