| 新型室温离子液体六烷基胍盐的制备及性质 |
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| 引用本文： | 段海峰,张所波,林英杰,邱志明,王宗睦.新型室温离子液体六烷基胍盐的制备及性质[J].高等学校化学学报,2003,24(11):2024-2026. |
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| 作者姓名： | 段海峰 张所波 林英杰 邱志明 王宗睦 |
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| 作者单位： | 1. 中国科学院长春应用化学研究所高分子物理与化学国家重点实验室, 长春 130022;
2. 吉林大学化学学院, 长春 130061 |
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| 摘 要： | 近年来 ,离子液体 (IL)作为“绿色”溶剂受到学术和工业界的关注 .英国 BP公司和法国的 IFP等研究机构从 2 0世纪 80年代起就开始探索离子液体作为溶剂与催化剂的可能性 ,至今在离子液体体系中已实现了许多催化反应 1～ 5] .室温离子液体 (RTIL S)是指在常温下呈液态的熔盐体系 .通常由烷基吡啶或双烷基咪唑季铵阳离子与氯铝酸根、氟硼酸根及氟磷酸根等阴离子组成 .在季铵盐类离子液体中 ,咪唑盐的合成和应用研究尤为突出 .目前 ,对于既可作为溶剂又可作为催化剂的室温离子液体的合成和应用已成为研究热点 6 ] ,如室温离子液体 EMI…
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| 关 键 词： | 室温离子液体 六烷基胍盐 合成 |
| 文章编号： | 0251-0790(2003)11-2024-03 |
| 收稿时间： | 2002-09-20 |
Synthesis and Properties of a Novel Room-temperature Ionic Liquid Hexaa lkylguanidium Salts |
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| DUAN Hai-Feng ,ZHANG Suo-Bo ,LIN Ying-Jie ,QIU Zhi-Ming ,WANG Zong-Mu.Synthesis and Properties of a Novel Room-temperature Ionic Liquid Hexaa lkylguanidium Salts[J].Chemical Research In Chinese Universities,2003,24(11):2024-2026. |
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| Authors: | DUAN Hai-Feng ZHANG Suo-Bo LIN Ying-Jie QIU Zhi-Ming WANG Zong-Mu |
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| Institution: | 1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2. College of Chemistry, Jilin University, Changchun 130023, China |
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| Abstract: | The synthesis and properties of a novel room-temperature ionic liquid hexaalkylguanidium salts 4 and 5 were reported. The reaction of 1,3-dimethyl-2-imidazolidinon with POCl 3 and n-BuNH 2 afforded to pentaalkyl-guanidine(2), which reacted with CH 3I, generated hexaalkylguanidium(3). The hexaalkylguanidium salts 4 and 5 were synthesized by the reaction of hexaalkylguanidium(3) with KPF 6, AgBF 4 respectively. The results showed that both compounds 4 and 5 were room-temperature ionic liquids. The structures of these compounds were determined by 1H NMR, 13C NMR, IR and MS spectra data. Compounds 4 and 5 were found to have better solublities in organic solvents and better thermal stabilities. |
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| Keywords: | Room-temperature ionic liquids Hexaalkylguanidium salts Synthesis |
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