| Zn-CCl2F2-H2O体系的低温基质隔离化学反应 |
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| 引用本文： | 王守文,古正,刘维铭,马洪,陈琪,郝身建.Zn-CCl2F2-H2O体系的低温基质隔离化学反应[J].无机化学学报,1991,7(3):349-350. |
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| 作者姓名： | 王守文 古正 刘维铭 马洪 陈琪 郝身建 |
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| 作者单位： | 四川大学化学系 成都610064
(王守文，古正，刘维铭，马洪，陈琪)，四川大学化学系 成都610064(郝身建) |
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| 基金项目： | 国家自然科学基金资助项目 |
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| 摘 要： | 低温基质隔离技术与各种光谱技术相结合,作为研究活性分子、分子结构、催化、光化学和制备新物质的一种重要方法,在国外已相当普遍,特别是在无机低温制备方面,由于涉及金属原子的低温化学反应具有简单性和自发性两大优点,近十多年来已有很大发展,专家们预言,低温无机合成化学,二十年后将成为一种重要的合成方法.目前国内尚未见有报道,本文介绍我们在这方面的初步尝试.
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| 关 键 词： | 锌 低温化学 基质隔离 |
| 收稿时间： | 1988/10/25 0:00:00 |
MI CHEMICAL REACTION IN THE SYSTEM OF Zn, F12 AND H2O AT 14K |
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| Wang Shouwen,Gu Zheng,Liu Weiming,Ma Hong,Chen Qi and Hao Shenjian.MI CHEMICAL REACTION IN THE SYSTEM OF Zn, F12 AND H2O AT 14K[J].Chinese Journal of Inorganic Chemistry,1991,7(3):349-350. |
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| Authors: | Wang Shouwen Gu Zheng Liu Weiming Ma Hong Chen Qi and Hao Shenjian |
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| Institution: | Department of Chemistry, Sichuan University, Chengdu 610064,Department of Chemistry, Sichuan University, Chengdu 610064,Department of Chemistry, Sichuan University, Chengdu 610064,Department of Chemistry, Sichuan University, Chengdu 610064,Department of Chemistry, Sichuan University, Chengdu 610064 and Department of Chemistry, Sichuan University, Chengdu 610064 |
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| Abstract: | We have studied the matrix isolation (MI) chemical reaction in the system of Zn, F12 and H2O at low temperature, using noble gas argon as a solid matrix. The cryogenic apparatus is a G-M refrigerator, which can reach a temperature of 14K. The sample is prepared by co-condensation method and monitored by a infrared spectrometer. From the observations, it is sure that the reaction in the system have taken place, we suggest that the products are F2C = O:Zn and ZnCl2. |
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| Keywords: | matrix isolation cryochemistry metal vapour synthesis zlnc |
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