| Synthesis, Structure and Biological Activities of Novel Triazole Compounds Containing N,N-Dialkyldithiocarbamate Moiety |
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| 作者姓名： | 许良忠 建方方 时建刚 孙萍萍 焦奎 |
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| 作者单位： | New Materials & Function Coordination Chemistry Laboratory，Qingdao University of Science and Technology，Qingdao，Shandong 266042，China College of Chemistry and Chemical Engineering，Ocean University of China，Qingdao，Shandong 266003，China，New Materials & Function Coordination Chemistry Laboratory，Qingdao University of Science and Technology，Qingdao，Shandong 266042，China，New Materials & Function Coordination Chemistry Laboratory，Qingdao University of Science and Technology，Qingdao，Shandong 266042，China，New Materials & Function Coordination Chemistry Laboratory，Qingdao University of Science and Technology，Qingdao，Shandong 266042，China，New Materials & Function Coordination Chemistry Laboratory，Qingdao University of Science and Technology，Qingdao，Shandong 266042，China College of Chemistry and Chemical Engineering，Ocean University of China，Qingdao，Shandong 266003，China |
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| 基金项目： | Project supported by Educational Administration Key Project of Shandong Province (No. J01C05) and the Natural Science Foundation of Shandong Province (No. Y2002B06). |
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| 摘 要： | Introduction As an important type of fungicides, triazole compounds are highly efficient, low poisonous and inward absorbent.1-3 At present, the studies on triazole derivatives are mainly concentrated on compounds with triazole as the only active group. The report of triazole compounds that contain both triazole group and other active group in a single molecule has rarely been found. Dialkyl-substituted dithiocarbamate salts have also shown interesting biological effects.4 N,N-Dialkyldithio-…
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| 关 键 词： | 合成 晶体结构 生物活性 三唑化合物 N N-烷基二硫代氨基甲酸酯 杀菌剂 |
Synthesis, Structure and Biological Activities of Novel Triazole Compounds Containing N,N-Dialkyldithiocarbamate Moiety |
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| XU,Liang-Zhonga,b JIAN,Fang-Fanga SHI,Jian-Ganga SUN,Ping-Pinga JIAO,Kui,a,b a New Materials & Function Coordination Chemistry Laboratory,Qingdao University of Science and Technology,Qingdao,Shandong ,China b College of Chemistry and Chemical Engineering,Ocean University of China,Qingdao,Shandong ,China.Synthesis, Structure and Biological Activities of Novel Triazole Compounds Containing N,N-Dialkyldithiocarbamate Moiety[J].Chinese Journal of Chemistry,2004,22(7):698-701. |
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| Authors: | XU Liang-Zhonga b JIAN Fang-Fanga SHI Jian-Ganga SUN Ping-Pinga JIAO Kui a b a New Materials & Function Coordination Chemistry Laboratory Qingdao University of Science and Technology Qingdao Shandong China b College of Chemistry and Chemical Engineering Ocean University of China Qingdao Shandong China |
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| Institution: | XU,Liang-Zhonga,b JIAN,Fang-Fanga SHI,Jian-Ganga SUN,Ping-Pinga JIAO,Kui*,a,b a New Materials & Function Coordination Chemistry Laboratory,Qingdao University of Science and Technology,Qingdao,Shandong 266042,China b College of Chemistry and Chemical Engineering,Ocean University of China,Qingdao,Shandong 266003,China |
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| Abstract: | The two compounds, 2, 2‐dimethy1‐4‐S‐(N,N‐ dimethyldithiocarbamato)‐5‐(1, 2, 4‐triazol‐1‐yl)‐propione (1) and 2, 2‐dimethyl‐4‐S‐(N,N,‐diethyldithiocarbamato)‐5‐(1, 2, 4‐triazol‐1‐yl)‐3‐propione (2), were prepared by reacting N,N‐dialkyldithiocarbamate sodium with 2, 2‐dimethyl‐4‐bromo‐5‐(1, 2, 4‐triazol‐l‐yl)‐propione. Their structures were identified by elemental analysis, IR and 1H NMR spectroscopy. The structure of 1 has been determined by X‐ray single crystal structure analysis. It crystallizes in monoclinic system with space group P21/c, a=1. 2315(3) nm, b=1.2057(2) nm, c =1.2532(3) nm, β=118.55(3)°, 2=4, V=1.6345(6) nm3, Dc=1.221 g/cm3, p=0.324 mm ?1, F(000)=640. final R1 =0.0449. There is obvious potentially weak C‐H···N intermolecular interaction in the crystal, which stabilizes the crystal structure. The result of the biological test showed that the two compounds have fungistasis and plant growth regulating activities. |
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| Keywords: | N N-dialkyldithiocarbamate 1 2 4-triazole crystal structure biological activity |
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