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Response surface methodology for the optimization of the ultrasonic-assisted rhamnolipid treatment of oily sludge
Authors:Chong Liu  Xuefei Hu  Qi Xu  Simin Zhang  Pengyan Zhang  Huanliang Guo  Yongjun You  Zhengjie Liu
Institution:1. State Key Laboratory of Heavy Oil Processing, Beijing Key Laboratory of Oil & Gas Pollution Control, Institute of Chemical Engineering and Environment, China University of Petroleum-Beijing, Beijing 102249, PR China;2. Institute of Water Resource and Architectural Engineering, Tarim University, Alar, Xinjiang 843300, PR China;3. Shenzhen Shenshui Ecological & Environmental Technology Co., Ltd., Shenzhen 518000, PR China
Abstract:This study investigates the recovery of oily sludge using ultrasound-assisted rhamnolipids and uses oil recovery yield as an evaluation index. The Box–Behnken response surface method was employed to investigate the individual and interactive effects of four different operating factors: frequency, dosage, liquid–solid ratio, and stirring speed. The model optimization results showed that the order of degree of influence of these four factors is frequency > liquid–solid ratio > dosage > stirring speed. The mathematical model predicted the highest oil recovery yield as 92.27%, which was highly accurate (in the 95% confidence interval) as from the experimental results, the highest oil recovery yield was 89.95% under optimal reaction conditions (frequency = 25.58 kHz, dosage = 150.45 mg/L, liquid–solid ratio = 4.1:1 mL/g, and stirring speed = 407 rpm). Thus, the deviation from the prediction model was only 2.32%, indicating that this method provides a theoretical basis for the treatment of oily sludge and can be implemented for practical application in Huaidong in the Xinjiang Province.
Keywords:Rhamnolipid  Ultrasound  Response surface  Oily sludge  Biosurfactant  CMC"}  {"#name":"keyword"  "$":{"id":"k0035"}  "$$":[{"#name":"text"  "_":"critical micelle concentration  CV"}  {"#name":"keyword"  "$":{"id":"k0045"}  "$$":[{"#name":"text"  "_":"coefficient of variance  IFT"}  {"#name":"keyword"  "$":{"id":"k0055"}  "$$":[{"#name":"text"  "_":"interfacial tension  PHC"}  {"#name":"keyword"  "$":{"id":"k0065"}  "$$":[{"#name":"text"  "_":"petroleum hydrocarbon  RH"}  {"#name":"keyword"  "$":{"id":"k0075"}  "$$":[{"#name":"text"  "_":"rhamnolipid  SARA"}  {"#name":"keyword"  "$":{"id":"k0085"}  "$$":[{"#name":"text"  "_":"saturates  aromatics  resins  and asphaltene  US"}  {"#name":"keyword"  "$":{"id":"k0095"}  "$$":[{"#name":"text"  "_":"ultrasonic  C  I  "}  {"#name":"keyword"  "$":{"id":"k0105"}  "$$":[{"#name":"text"  "_":"confidence interval
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