Synthesis and X-ray crystallographic structures of [HGa(NMe2)2]2 and [PhGa(NHNMe2)2]2, and room-temperature conversions of [HGa(NMe2)2]2 to (HGaNH)n and (HGaNMe)n |
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| Authors: | Bing Luo |
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| Institution: | Department of Chemistry, University of Minnesota, 207 Pleasant St., SE Minneapolis, MN 55455, USA |
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| Abstract: | The reactivity of bis(dimethylamido) complexes of phenyl- and hydridogallium with ammonia, dimethylamine and 1,1-dimethylhydrazine is described. Synthesis of the starting gallium hydride, HGa(NMe2)2]2, was achieved in nearly quantitative yield from the reaction of HGaCl2(quinuclidine) with LiNMe2. In neat ammonia or methylamine at room temperature both dimethylamido ligands in HGa(NMe2)2]2 were substituted by a single equivalent of NH3 or MeNH2 to produce amorphous (HGaNH)n or (HGaNMe)n, respectively. In contrast, the reaction of PhGa(NMe2)2]2 with neat Me2NNH2, at room temperature consumed two equivalents of the substituted hydrazine to form PhGa(NHNMe2)2]2 in a 73% yield. Single crystal X-ray crystallographic analyses of HGa(NMe2)2]2 and PhGa(NHNMe2)2]2 establish that in the solid state both compounds adopt a cyclic Ga-N-Ga-N structure with a crystallographic center of symmetry located at the center of the ring. |
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| Keywords: | Gallium Amide Hydrazide Hydride Synthesis Structure |
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