|
|||||
|
|
Formation of an η-allyl and a cyclic γ-hydroxyalkyl complex of molybdenum from reaction of MoH2(η-cyclopentadienyl)2 with homoallyl alcohol |
|
| Authors: | Makoto Minato Susumu Hiratsuka Takashi Ito |
| Institution: | a Department of Materials Chemistry, Graduate School of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan b Research Laboratory of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan |
| Abstract: | The reaction of Cp2MoH2 (Cp=η5-C5H5) with homoallyl alcohol in the presence of a protonic acid afforded a cationic η3-crotyl molybdenum complex and a cyclic α-methyl-γ-hydroxypropyl molybdenum complex. This reaction proceeds via the stepwise formation of the cyclic complex, followed by formation of the η3-crotyl complex. |
| Keywords: | Molybdenum Hydrido complex Homoallyl alcohol |
| 本文献已被 ScienceDirect 等数据库收录！ | |