| 四氮唑衍生物构筑的金刚烷拓扑金属-有机骨架的合成、表征及荧光性质 |
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| 引用本文： | 秦俊生,兰亚乾,王海宁,李连杰,王新龙,孙秀云,邵奎占,苏忠民.四氮唑衍生物构筑的金刚烷拓扑金属-有机骨架的合成、表征及荧光性质[J].高等学校化学学报,2011,32(3):683-687. |
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| 作者姓名： | 秦俊生 兰亚乾 王海宁 李连杰 王新龙 孙秀云 邵奎占 苏忠民 |
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| 作者单位： | 1. 东北师范大学化学学院, 功能材料化学研究所, 长春 130024;
2. 吉林化工学院应用化学系, 吉林 132022 |
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| 基金项目： | 国家自然科学基金，长江学者和创新团队发展计划，吉林省科技发展计划青年基金，东北师范大学"十一五"科技创新培育基金，教育部新教师博士点基金，国家博士后基金，东北师范大学博士后基金 |
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| 摘 要： | 5-氨基四氮唑(HATZ)与硝酸锌通过溶剂热反应得到了一个新的化合物，Zn(ATZ)2]?DMA (1)，并对其进行了X射线粉末衍射，红外和元素分析表征. 单晶X射线分析表明，该化合物展示了一个三维四连接金刚烷拓扑的微孔金属有机框架，沿100]方向的孔道维度大约12.7 ? × 8.9 ?，PLATON计算表明孔体积为53.5%. 此外，荧光光谱测试表明化合物在室温下显示较强的蓝色荧光性质.
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| 关 键 词： | 金属-有机骨架 四氮唑 金刚烷拓扑 荧光 |
| 收稿时间： | 2010-10-14 |
Synthesis,Characterization and Luminescence of a New Diamondoid MoF Based on Tetrazole Derivative |
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| QIN Jun-Sheng,LAN Ya-Qian,WANG Hai-Ning,LI Lian-Jie,WANG Xin-Long,SUN Xiu-Yun,SHAO Kui-Zhan,SU Zhong-Min.Synthesis,Characterization and Luminescence of a New Diamondoid MoF Based on Tetrazole Derivative[J].Chemical Research In Chinese Universities,2011,32(3):683-687. |
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| Authors: | QIN Jun-Sheng LAN Ya-Qian WANG Hai-Ning LI Lian-Jie WANG Xin-Long SUN Xiu-Yun SHAO Kui-Zhan SU Zhong-Min |
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| Institution: | 1. Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China;
2. Department of Applied Chemistry, Jilin Institute of Chemical Technology, Jilin 132022, China |
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| Abstract: | A self-assembly reaction between the ligand 5-amino-tetrazole (HATZ) and zinc (Ⅱ) nitrate led to the formation of Zn(ATZ)2·DMA( 1 ), which was characterized by X-ray powder diffraction( XRPD), IR spectrum and elemental analysis. Single-crystal X-ray analysis indicates that compound 1 exhibits a 3D microporous diamondoid (dia) topology with a channel dimension of about 1.27 nm ×0. 89 nm along the 100] direction. PLATON calculations show a void space of ca. 53. 5% per unit cell. The luminescent spectrum of compound 1 shows a strong blue fluorescence at room temperature. |
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| Keywords: | Metal-organic framework Tetrazole Diamondoid topology Luminescence |
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