Oxygen activation on metallic centers and oxidizing abilities of such oxygen期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Oxygen activation on metallic centers and oxidizing abilities of such oxygen

Authors:	Elena A Zaburdaeva Viktor A Dodonov Larisa P Stepovik

Institution:	Nizhny Novgorod State University, 23, Gagarina pr., 603950, Nizhny Novgorod, Russia

Abstract:	It was shown that metallcontaining peroxides such as XOOOBu-t X = (t-BuO)₂Al, (t-BuO)₃Ti] generate molecular oxygen in the electron-excited singlet state (¹O₂). These ozonides and η²-peroxocomplex Ph₃Bi(η²O₂) demonstrate high oxidative activity towards some classes of organic substances under mild conditions (20 °C).

Keywords:	Metallcontaining peroxides Electron-excited singlet oxygen Oxidation Hydrocarbons Nitroxyl radicals Sulfides Sulfones
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