Synthesis,Characterization, and Magnetic Properties of Novel Cobalt(II) and Copper(II) Complexes with 5‐(Isonicotinamido)isophthalate Ligand |
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Authors: | Xiu‐Jun Deng Wen Gu Li Wang Ling‐Fei Zeng Prof Dr Xin Liu |
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Institution: | Department of Chemistry, Nankai University, Tianjin, 300071, P. R. China |
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Abstract: | Two new complexes, {Co(INAIP) · H2O] · 2H2O}n ( 1 ), and {Cu(INAIP)] · H2O}n ( 2 ) H2INAIP = 5‐(isonicotinamido)isophthalic acid] were synthesized under hydrothermal conditions, and characterized by single‐crystal X‐ray structure determination, thermogravimetric analysis, X‐ray powder diffraction, and magnetic studies. In complex 1 both CoII atoms and INAIP2– ligands act as four‐connected node, whereas in 2 both CuII atoms and INAIP2– ligands act as three‐connected node. |
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Keywords: | Cobalt Copper 5‐(Isonicotinamido)isophthalate Magnetic properties Metal‐organic frameworks |
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