Reaktion von (R,R)‐(N,N′)‐Diisopropylcyclohexyl‐1,2‐diamin mit Me2MCl (M = Ga,In) |
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| Authors: | Navabeeh Nami Chamazi Majid M Heravi Thees Breyhan Bernhard Neumüller Prof Dr |
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| Institution: | 1. Marburg, Fachbereich Chemie der Philipps‐Universit?t;2. Marburg, Fachbereich Chemie der Philipps‐Universit?tFachbereich Chemie der Universit?t, D‐35032 Marburg, Fax: int‐6421/2825653 |
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| Abstract: | Reaction of (R,R)‐(N,N′)‐Diisopropylcyclohexyl‐1,2‐diamine with Me2MCl (M = Ga, In) (R,R)‐(N,N′)‐Diisopropylcyclohexyl‐1,2‐diamine (H2L) was reacted with Me2GaCl and Me2InCl in boiling toluene, respectively. In both cases the salt Me2M(H2L)]Me2MCl2] M = Ga ( 1 ), In ( 2 )] was formed. 1 and 2 were characterized by NMR and vibrational spectroscopy. In addition, an X‐ray structure determination was applied on 2 . According to the spectroscopical and structural findings 1 and 2 consist of cations Me2M(H2L)]+ and anions Me2MCl2]?. |
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| Keywords: | Gallium Indium Chiral Ligand Crystal Structure |
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