Host-Guest Interactions of Cyclopentanocucurbit[6]uril with Alkyl Imidazolium Hydrochlorides

The host-guest interactions between cyclopentanocucurbit-6]uril(CyP₆Q6]) as host and six alkyl imidazolium hydrochloride as guests(g1, g2, g3, g4, g5, and g6) have been studied by various techniques, such as ¹H NMR spectroscopy, isothermal titration calorimetry, mass spectrometry, and single-crystal X-ray diffraction analysis. The experimental results showed that CyP₆Q6] formed 1:1 inclusion complexes with each of guests g1-g6. The part of the guest entered the cavity of CyP₆Q6] changes as the alkyl chain increases in length. It can be seen that the length of the alkyl chain plays a key role in determining the mode of host-guest interactions.