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Ion pairing, H-bonding, and π–π interactions in copper(II) complex-organo-networks derived from a proton-transfer compound of the 1,10-phenanthroline-2,9-dicarboxylic acid |
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| Authors: | Abolghasem Moghimi Robabeh Alizadeh Hossein Aghabozorg Abbas Shockravi M Carla Aragoni Francesco Demartin Francesco Isaia Vito Lippolis Andrew Harrison A Shokrollahi Mojtaba Shamsipur |
| Institution: | aDepartment of Chemistry, Imam Hossein University, P.O. Box 16575-347, Tehran, Iran bDepartment of Chemistry, Teacher Training University, P.O. Box 15815-3587, Tehran, Iran cDipartimento di Chimica Inorganica ed Analitica, Universita? di Cagliari, S. S. 554 bivio per Sestu, I-09042, Monserrato, Italy dDipartimento di Chimica Strutturale e Stereochimica Inorganica, Via G. Venezian 21, I-20133, Milano, Italy eDepartment of Chemistry, The University of Edinburgh, West Mains Road, EH9 3JJ Edinburgh, UK fDepartment of Chemistry, Razi University, Kermanshah, Iran |
| Abstract: | The one-pot reaction between the novel proton transfer compound (pydaH2)2+(phendc)2?, LH2, and Cu(II) afforded the compounds (pydaH)2Cu(phendc)2]·10H2O, 1, and (pydaH)2Cu(phendc)(phendcH)]2·5H2O, 2, where pyda=2,6-diaminopyridine, and phendcH2=1,10-phenanthroline-2,9-dicarboxylic acid. The single crystal X-ray diffraction analysis of 1 and 2 revealed that these are two novel self-assembled 3D Cu(II) complex-organo-networks, in which (pydaH)+ ions and Cu(phendc)2]2? or |
| Keywords: | Copper 1 10-Phenanthroline-2 9-dicarboxylic acid 2 6-Pyridinediamine Hydrogen bonds Ion pairs |
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