| 化学键组装稀土/无机/有机聚合物杂化光功能材料的最新研究进展 |
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| 引用本文： | 闫冰,乔晓菲,盛凯,王小龙,郭敏,邵燕飞.化学键组装稀土/无机/有机聚合物杂化光功能材料的最新研究进展[J].中国科学:化学,2012(9):1278-1288. |
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| 作者姓名： | 闫冰 乔晓菲 盛凯 王小龙 郭敏 邵燕飞 |
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| 作者单位： | 同济大学化学系,上海200092 |
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| 基金项目： | 国家自然科学基金（20301013、20671072、20971100）; 教育部新世纪人才支持计划项目（NCET-08-0398）; 同济大学科技发展基金项目的资助 致谢感谢国家自然科学基金（20301013、20671072、20971100）,教育部新世纪人才支持计划项目（NCET-08-0398）和同济大学科技发展基金项目的资助.感谢研究生王前明、赵利民、李亚娟、郭磊等同学的研究工作. |
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| 摘 要： | 本文针对近五年来光功能稀土/无机/有机聚合物杂化材料的最新进展进行了评述,其重点着眼于高分子化合物作为构筑基元的发光稀土杂化材料体系的化学键组装.内容主要涉及稀土有机高分子杂化材料、配位键构筑的稀土/无机/有机高分子杂化材料、共价键构筑的稀土/无机/有机高分子杂化材料、自由基聚合构筑的稀土/无机/有机高分子杂化材料几个重要方面.主要结合我们自己的近期研究工作,通过系统总结来展现该领域的研究现状并提出未来展望.
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| 关 键 词： | 稀土 杂化材料 聚合物构筑基元 化学键组装 光物理 |
Recent progress in photoactive rare earth/inorganic/organic polymeric hybrid materials with covalently bonded assembly |
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| YAN Bing＊,QIAO XiaoFei,SHENG Kai,WANG XiaoLong,GUO Min,SHAO YanFei.Recent progress in photoactive rare earth/inorganic/organic polymeric hybrid materials with covalently bonded assembly[J].Scientia Sinica Chimica,2012(9):1278-1288. |
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| Authors: | YAN Bing＊ QIAO XiaoFei SHENG Kai WANG XiaoLong GUO Min SHAO YanFei |
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| Institution: | Department of Chemistry, Tongji University, Shanghai 200092, China |
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| Abstract: | In this paper, the recent progress on the photoactive rare earth/inorganic/organic polymeric hybrid materials has been reviewed, whose emphasis is put on the chemical bonded assembly of luminescent rare earth hybrid systems with macromolecular compounds as building block. The contents involve rare earth polymeric hybrid materials, coordinated bonding assembled rare earth/inorganic/organic polymeric hybrid materials, covalently bonding assembled rare earth/inorganic/organic polymeric hybrid materials, and radical polymerized assembled rare earth/inorganic/organic polymeric hybrid materials. Here we mainly summarize the work of our group. Through the systematical summary, the research facts and future perspect are discussed. |
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| Keywords: | rare earth hybrid material polymer building block chemically bonded assembly photophysics |
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